Concrete durability
has been defined by the American Concrete Institute as its resistance to
weathering action, chemical attack, abrasion and other degradation
processes.
Durability
is the ability to last a long time without significant deterioration. A
durable material helps the environment by conserving resources and
reducing wastes and the environmental impacts of repair and replacement.
Construction and demolition waste contribute to solid waste going to
landfills. The production of new building materials depletes natural
resources and can produce air and water pollution The design service
life of most buildings is often 30 years, although buildings often last
50 to 100 years or longer. Most concrete and masonry buildings are
demolished due to obsolescence rather than deterioration. A concrete
shell can be left in place if a building use or function changes or when
a building interior is renovated. Concrete, as a structural material
and as the building exterior skin, has the ability to withstand nature’s
normal deteriorating mechanisms as well as natural disasters.
Durability
of concrete may be defined as the ability of concrete to resist
weathering action, chemical attack, and abrasion while maintaining its
desired engineering properties. Different concretes require different
degrees of durability depending on the exposure environment and
properties desired. For example, concrete exposed to tidal seawater will
have different requirements than an indoor concrete floor. Concrete
ingredients, their proportioning, interactions between them, placing and
curing practices, and the service environment determine the ultimate
durability and life of concrete.
Seawater
Exposure: Concrete has been used in seawater exposures for decades
with excellent performance. However, special care in mix design and
material selection is necessary for these severe environments. A
structure exposed to seawater or seawater spray is most vulnerable in
the tidal or splash zone where there are repeated cycles of wetting and
drying and/or freezing and thawing. Sulfates and chlorides in seawater
require the use of low permeability concrete to minimize steel corrosion
and sulfate attack. A cement resistant to sulfate exposure is helpful.
Proper concrete cover over reinforcing steel must be provided, and the
water-cementitious ratio should not exceed 0.40.
Chloride
Resistance and Steel Corrosion: Chloride present in plain concrete that
does not contain steel is generally not a durability concern. Concrete
protects embedded steel from corrosion through its highly alkaline
nature. The high pH environment in concrete (usually greater than 12.5)
causes a passive and noncorroding protective oxide film to form on
steel. However, the presence of chloride ions from deicers or seawater
can destroy or penetrate the film. Once the chloride corrosion threshold
is reached, an electric cell is formed along the steel or between steel
bars and the electrochemical process of carrions begins
The
resistance of concrete to chloride is good; however, for severe
environments such as bridge decks, it can be increase by using a low
water-cementitious ratio (about 0.40), at least seven days of moist
curing, and supplementary cementitious materials such as silica fume, to
reduce permeability. Increasing the concrete cover over the steel also
helps slow down the migration of chlorides. Other methods of reducing
steel corrosion include the use of corrosion inhibiting admixtures,
epoxy-coated reinforcing steel, surface treatments, concrete overlays,
and cathodic protection
Resistance
to Alkali-Silica Reaction (ASR): ASR is an expansive reaction between
reactive forms of silica in aggregates and potassium and sodium alkalis,
mostly from cement, but also from aggregates, pozzolans, admixtures,
and mixing water. The reactivity is potentially harmful only when it
produces significant expansion. Indications of the presence of
alkali-aggregate reactivity may be a network of cracks, closed or
spalling joints, or movement of portions of a structure. ASR can be
controlled through proper aggregate selection and/or the use of
supplementary cementitious materials (such as fly ash or slag cement) or
blended cements proven by testing to control the reaction
Abrasion
Resistance: Concrete is resistant to the abrasive affects of ordinary
weather. Examples of severe abrasion and erosion are particles in
rapidly moving water, floating ice, or areas where steel studs are
allowed on tires. Abrasion resistance is directly related to the
strength of the concrete. For areas with severe abrasion, studies show
that concrete with compressive strengths of 12,000 to 19,000 psi work
well.
Concrete cracking
Concrete,
like most materials, will shrink slightly when it dries out. Common
shrinkage is about 1/16th of an inch in a 10-foot length of concrete.
The reason contractors place joints in concrete pavements and floors is
to allow the concrete to crack in a neat, straight line at the joint,
where concrete cracks due to shrinkage are expected to occur. Control or
construction joints are also placed in concrete walls and other
structures.
Surface spalling
Concrete spalling (or flaking) can be prevented. It occurs due to one or more of the following reasons.
1.)
In cold climates subjected to freezing and thawing, concrete surfaces
have the potential to spall if the concrete is not air-entrained.
2.)Too
much water in the concrete mix will produce a weaker, more permeable
and less durable concrete. The water-cementitious ratio should be as low
as possible (0.45 or less).
3.)
Concrete finishing operations should not begin until the water sheen on
the surface is gone and the excess bleed water on the surface has had a
chance to evaporate. If this excess water is worked into the concrete
because finishing operations have begun too soon, the concrete on the
surface will have too high of a water content and this surface will be
weaker and less durable.
High
Humidity and Wind-Driven Rain: Concrete is resistant to wind-driven
rain and moist outdoor air in hot and humid climates because it is
impermeable to air infiltration and wind-driven rain. Moisture that
enters a building must come through joints between concrete elements.
Annual inspection and repair of joints will minimize this potential.
More importantly, if moisture does enter through joints, it will not
damage the concrete. Good practice for all types of wall construction is
to have permeable materials that breathe (are allowed to dry) on at
least one surface and to not encapsulate concrete between two
impermeable surfaces. Concrete will dry out if not covered by
impermeable treatments.
Portland
cement plaster (stucco) should not be confused with the exterior
insulation finish systems (EIFS) or synthetic stucco systems that have
become popular but may have performance problems, including moisture
damage and low impact-resistance. Synthetic stucco is generally a
fraction of the thickness of portland cement stucco, offering less
impact resistance. Due to its composition, it does not allow the inside
of a wall to dry when moisture gets trapped.
inside.
Trapped moisture eventually rots insulation, sheathing, and wood
framing. It also corrodes metal framing and metal attachments. There
have been fewer problems with EIFS used over solid bases such as
concrete or masonry because these substrates are very stable and are not
subject to rot or corrosion.
Ultraviolet
Resistance: The ultraviolet portion of solar radiation does not harm
concrete. Using colored pigments in concrete retains the color in
concrete long after paints have faded due to the sun’s effects.
Inedible: Vermin
and insects cannot destroy concrete because it is inedible. Some softer
materials are inedible but still provide pathways for insects. Due to
its hardness, vermin and insects will not bore through concrete. Gaps in
exterior insulation to expose the concrete can provide access for
termite inspectors.
Moderate to Severe Exposure Conditions for Concrete:
The following are important exposure conditions and deterioration
mechanisms in concrete. Concrete can withstand these effects when
properly designed. The Specifier’s Guide for Durable Concrete is
intended to provide sufficient information to allow the practitioner to
select materials and mix design parameters to achieve durable concrete
in a variety of environments.
Resistance to Freezing and Thawing:
The most potentially destructive weathering factor is freezing and
thawing while the concrete is wet, particularly in the presence of
deicing chemicals. Deterioration is caused by the freezing of water and
subsequent expansion in the paste, the aggregate particles, or both.
With
the addition of an air entrainment admixture, concrete is highly
resistant to freezing and thawing. During freezing, the water displaced
by ice formation in the paste is accommodated so that it is not
disruptive; the microscopic air bubbles in the paste provide chambers
for the water to enter and thus relieve the hydraullic pressure
generated. Concrete with a low water-cementitious ratio (0.40 or lower)
is more durable than concrete with a high water-cementitious ratio (0.50
or higher). Air-entrained concrete with a low water-cementitious ratio
and an air content of 5 to 8% will withstand a great number of cycles of
freezing and thawing without distress.
Chemical Resistance:
Concrete is resistant to most natural environments and many chemicals.
Concrete is virtually the only material used for the construction of
wastewater transportation and treatment facilities because of its
ability to resist corrosion caused by the highly aggressive contaminants
in the wastewater stream as well as the chemicals added to treat these
waste products.
However
concrete is sometimes exposed to substances that can attack and cause
deterioration. Concrete in chemical manufacturing and storage facilities
is specially prone to chemical attack. The effect of sulfates and
chlorides is discussed below. Acids attack concrete by dissolving the
cement paste and calcareous aggregates. In addition to using concrete
with a low permeability, surface treatments can be used to keep
aggressive substances from coming in contact with concrete. Effects of
Substances on Concrete and Guide to Protective Treatments discusses the
effects of hundreds of chemicals on concrete and provides a list of
treatments to help control chemical attack.
Resistance to Sulfate Attack:
Excessive amounts of sulfates in soil or water can attack and destroy a
concrete that is not properly designed. Sulfates (for example calcium
sulfate, sodium sulfate, and magnesium sulfate) can attack concrete by
reacting with hydrated compounds in the hardened cement paste. These
reactions can induce sufficient pressure to cause disintegration of the
concrete.
Like
natural rock such as limestone, porous concrete (generally with a high
water-cementitious ratio) is susceptible to weathering caused by salt
crystallization. Examples of salts known to cause weathering of concrete
include sodium carbonate and sodium sulfate.
Sulfate
attack and salt crystallization are more severe at locations where the
concrete is exposed to wetting and drying cycles, than continuously wet
cycles. For the best defense against external sulfate attack, design
concrete with a low water to cementitious material ratio (around 0.40)
and use cements specially formulated for sulfate environments
Sulfate attack in concrete and mortar
Sulfate attack can be ‘external’ or ‘internal’.
External: due to penetration of sulfates in solution, in groundwater for example, into the concrete from outside.
External: due to penetration of sulfates in solution, in groundwater for example, into the concrete from outside.
Internal:
due to a soluble source being incorporated into the concrete at the
time of mixing, gypsum in the aggregate, for example.
External sulfate attack
This
is the more common type and typically occurs where water containing
dissolved sulfate penetrates the concrete. A fairly well-defined
reaction front can often be seen in polished sections; ahead of the
front the concrete is normal, or near normal. Behind the reaction front,
the composition and microstructure of the concrete will have changed.
These changes may vary in type or severity but commonly include:
· Extensive cracking
· Expansion
· Loss of bond between the cement paste and aggregate
·
Alteration of paste composition, with monosulfate phaseconverting to
ettringite and, in later stages, gypsum formation The necessary
additional calcium is provided by the calcium hydroxide and calcium
silicate hydrate in the cement paste
The effect of these changes is an overall loss of concrete strength.
The above effects are typical of attack by solutions of sodium sulfate or potassium sulfate. Solutions containing magnesium sulfate are generally more aggressive, for the same concentration. This is because magnesium also takes part in the reactions, replacing calcium in the solid phases with the formation of brucite (magnesium hydroxide) and magnesium silicate hydrates. The displaced calcium precipitates mainly as gypsum.
Other sources of sulfate which can cause sulfate attack include:
· Seawater
·
Oxidation of sulfide minerals in clay adjacent to the concrete – this
can produce sulfuric acid which reacts with the concrete
·
Bacterial action in sewers – anaerobic bacterial produce sulfur dioxide
which dissolves in water and then oxidizes to form sulfuric acid
·
In masonry, sulfates present in bricks and can be gradually released
over a long period of time, causing sulfate attack of mortar, especially
where sulfates are concentrated due to moisture movement
· Internal sulfate attack
Occurs
where a source of sulfate is incorporated into the concrete when mixed.
Examples include the use of sulfate-rich aggregate, excess of added
gypsum in the cement or contamination. Proper screening and testing
procedures should generally avoid internal sulfate attack.
· Delayed ettringite formation
Delayed ettringite formation (DEF) is a special case of internal sulfate attack.
Delayed ettringite formation has been a significant problem in many countries. It occurs in concrete which has been cured at elevated temperatures, for example, where steam curing has been used. It was originally identified in steam-cured concrete railway sleepers (railroad ties). It can also occur in large concrete pours where the heat of hydration has resulted in high temperatures within the concrete.
Delayed ettringite formation has been a significant problem in many countries. It occurs in concrete which has been cured at elevated temperatures, for example, where steam curing has been used. It was originally identified in steam-cured concrete railway sleepers (railroad ties). It can also occur in large concrete pours where the heat of hydration has resulted in high temperatures within the concrete.
DEF causes expansion of the concrete due to ettringite formation within the paste and can cause serious damage to concrete structures. DEF is not usually due to excess sulfate in the cement, or from sources other than the cement in the concrete. Although excess sulfate in the cement would be likely to increase expansion due to DEF, it can occur at normal levels of cement sulfate.
A key point in understanding DEF is that ettringite is destroyed by heating above about 70 C.
A definition of delayed ettringite formation DEF occurs if the ettringite which normally forms during hydration is decomposed, then subsequently re-forms in the hardened concrete.
Damage to the concrete occurs when the ettringite crystals exert an expansive force within the concrete as they grow.
In
normal concrete, the total amount of ettringite which forms is
evidently limited by the sulfate contributed by the cement initially. It
follows that the quantity of ettringite which forms is relatively
small. Ettringite crystals form widely-dispersed throughout the paste.
If expansion causes cracking, ettringite may subsequently form in the
cracks but this does not mean the ettringite in the cracks caused the
cracks initially.
Conditions necessary for DEF to occur are:
· High temperature (>65-70 C approx.), usually during curing but not necessarily
· Water: intermittent or permanent saturation aftercuring
· Commonly associated with alkali-silica reaction (ASR)
In laboratory tests, limestone coarse aggregate has been found to reduce expansion.
DEF usually occurs in concrete which has either been steam cured, or which reached a high temperature during curing as a result of the exothermic reaction of cement hydration.
DEF usually occurs in concrete which has either been steam cured, or which reached a high temperature during curing as a result of the exothermic reaction of cement hydration.
As
the curing temperature of concrete increases, ettringite normally
persists up to about 70 C. Above this temperature it decomposes. In
mature concrete, monosulfate is usually the main sulfate-containing
hydrate phase and this persists up to about 100 C. DEF could occur in
concrete which was heated externally, eg: from fire.
An ettringite molecule contains 32 molecules of water; ettringite formation therefore requires wet conditions DEF
and ASR appear to be closely linked; in one study (Diamond and Ong,
1994) a mortar made using limestone aggregate was cured at 95 C.
Subsequent ettringite formation within the paste was scarce and
expansion was minimal. However, if aggregate susceptible to ASR was used
instead of limestone, ettringite formation and expansion were both much
greater. This, and other studies, suggests that ASR is, or can be, a
precursor for DEF expansion.
The effect of cement composition on DEF is not well understood. Some factors correlate strongly but the causes are not clear. In laboratory tests, DEF expansion was shown to correlate positively with cement-related factors, including:
a. high sulfate
b. high alkali
c. high MgO
d. cement fineness
e. high C3A
f. high C3S
DEF is still by no means fully understood. For further reading on this subject, try:
The resistance to deformation that makes concrete a useful material means also that volume changes of the concrete itself can have important implications in use. Any potential growth or shrinkage may lead to complications, externally because of structural interaction with other components or internally when the concrete is reinforced. There may even be distress if either the cement paste or the aggregate changes dimension, with tensile stresses set up in one component and compressive stresses in the other. Cracks may be produced when the relatively low tensile strength of the concrete or its constituent materials is exceeded.
The resistance to deformation that makes concrete a useful material means also that volume changes of the concrete itself can have important implications in use. Any potential growth or shrinkage may lead to complications, externally because of structural interaction with other components or internally when the concrete is reinforced. There may even be distress if either the cement paste or the aggregate changes dimension, with tensile stresses set up in one component and compressive stresses in the other. Cracks may be produced when the relatively low tensile strength of the concrete or its constituent materials is exceeded.
Cracking
not only impairs the ability of a structure to carry its design load
but may also affect its durability and damage its appearance. In
addition, shrinkage and creep may increase deflections in one member of a
structure, adversely affecting the stability of the whole. These
factors have to be considered in design. Volume change of concrete is
not usually associated with changes that occur before the hardened state
is attained. Quality and durability, on the other hand, are dependent
on what occurs from the time the concrete mix has been placed in the
mold.
Settlement and Bleeding
Concrete
is said to be in a plastic state before it begins to set. The aggregate
is dispersed by the cement paste and the particles in the paste are
dispersed in the water. After placing, there is a period of settlement
when the particles come closer together; most of this settlement usually
occurs within an hour or so of placement. Total volume change may, in
extreme cases, amount to 1 per cent or more, but it is not of great
significance because the concrete is in a plastic or semiplastic state
and no appreciable stresses can result from these changes. During
settlement, water often appears at the surface, having exuded from the
plastic mass. This phenomenon is called bleeding.
Accumulation
of water at the top of a mass of concrete is often undesirable; for
example, when concrete is placed continuously in a deep form, the upper
part can gain progressively more water as the filling of the form
progresses, leading to relatively poor quality at the top. On the other
hand, the accumulation of some water at the surface is not always
undesirable because surface water is required to prevent plastic
shrinkage and to lubricate the tools used for finishing the surface.
Again, an excess of surface water may lead to a thin layer of slurry on
the finished surface and a weak susceptible layer on the surface of the
concrete. Care must be taken that finishing does not begin before the
bleeding period is over.
Settlement
may give rise to structural flaws. A layer of water may be left under
horizontal reinforcing bars so that half the area of contact between the
steel and concrete is lost. This problem can be eliminated by proper
vibration or revibration of the plastic concrete, care being taken not
to touch reinforcing. It must not be overlooked, however, that
settlement and bleeding do result in a reduction of water content. If
not offset by one of the undesirable features discussed, the effect is
beneficial to strength, permeability and volume stability.
Plastic Shrinkage
When
the evaporation rate exceeds the rate of bleeding and the free
settlement period is ended, a hydrostatic tension begins to develop
throughout the mass owing to the formation of menisci at the water
surfaces in the capillaries. This results in vertical as well as lateral
compressive forces and may be manifested in a slab by pattern cracking.
It is called plastic shrinkage cracking. Remedial measures may involve
sun shades and windbreaks, application of water sprays or application of
a curing compound to arrest evaporation.
Nature of Hydrated Portland Cement and Mechanism of Volume Change
Following
hydration and hardening, cement consists of a mixture of several
compounds, all chemically combined with water in different ways. The
compound that has the greatest influence on the characteristics of
hydrated cement, including shrinkage, is calcium silicate, which has a
large internal surface area of 25 to 50 thousand square yards per pound.
This internal surface is composed of the walls of the tiny pores and
fissures within the physical dimensions of the specimen. (It is the
character of this surface that makes hydrated cement an effective
cementing agent and provides the versatility of concrete in forming
bodies of high strength and almost any desired shape. When surfaces are
very close to each other there is a mutual gravitation-like attraction
that forms a strong “weld.” When the internal surface area is high the
many strong welds develop the strength and rigidity of the body.)
Thus
concrete is not a solid inert mass but a vast number of small pores or
capillaries that in total can account for up to 50 per cent of the
volume of the concrete. During curing the pores and capillaries are
usually full of water and no stresses exist. As drying takes place,
three mechanisms cause shrinkage:
1.
The unstable nature of newly-formed calcium silicate hydrate results in
shrinkage as drying occurs; the exact nature of this mechanism is not
clearly understood but it is permanent and irreversible;
2.
Compressive stresses are set up in the concrete because of the
development of menisci in the capillaries as drying progresses;
3. Energy changes occur at the surface of calcium silicate as the water evaporates.
These
mechanisms (phenomena) acting separately or in combination cause
initial drying shrinkage of the concrete. Part of it, 30 per cent or
more, is irreversible.
Autogenous Volume Changes and Expansive Cements
Before
volume changes resulting from drying or wetting of hardened concrete
are discussed, autogenous volume changes should be mentioned because
they occur where little or no change in total moisture content is
possible and are of particular importance in the interior of mass
concrete. Two opposing effects can be produced. As reaction between
water and the unhydrated cement proceeds, the actual volume of the solid
increases. This causes stresses through the set structure and results
in expansion. At later ages, the water available for the reaction will
decrease, resulting in self-desiccation of the cement paste and a
shrinkage ranging from 0.001 to more than 0.015 per cent.
The
increase in volume of some constituents during their formation has been
used as the basis for developing expansive cements. Some, specially
prepared, undergo relatively large expansions at early age so that if
used in concrete that is restrained they develop compressive stresses.
Later, when drying occurs, the resulting shrinkage that would have
developed is partly or completely offset, and compressive stresses no
longer exist in the concrete.
Volume Changes due to Moisture Changes
Although
the mechanism of volume change that occurs during moisture change is
not fully understood, much has been learned to provide useful
information for engineering purposes. When concrete is dried, the first
water to be removed causes no change in volume. This is considered to be
free water held in rather large “pores.” With continued drying,
shrinkage becomes quite large and at equilibrium in 50 per cent RH
values in excess of 0.10 per cent have been recorded for some concretes.
The above behaviour is somewhat similar to that of wood (in a
qualitative manner). Shrinkage values for neat cement paste have been
observed in excess of 0.40 per cent; the difference of this value from
that of concrete is due to various restraints. A large portion of
concrete is made up of relatively inert aggregate (from 3 to 7 times the
weight of cement) and this, together with reinforcement, reduces
shrinkage. In addition to internal restraints, some restraint arises
from non-uniform shrinkage within the concrete member itself. Moisture
loss takes place at the surface so that a moisture gradient is
established. The resultant differential shrinkage is associated with
internal stresses, tensile near the surface and compressive in the core,
and may result in warping or cracking.
If
concrete that has been allowed to dry in air at 50 per cent RH is
subsequently placed in water, it will swell. Not all initial shrinkage
obtained on drying is recovered, however, even after prolonged storage.
For the usual range of concretes the irreversible part of shrinkage is
about 30 to 60 per cent of total drying shrinkage, the lower value being
more common. Because shrinkage has such an influence on the performance
of concrete structures much work has been carried out to obtain
information on the factors affecting it.
Effect of Cement and Water Contents on Shrinkage
Water
content is probably the largest single factor influencing the shrinkage
of paste and concrete. Typical shrinkage values for concrete specimens
with a 5 to 1 aggregate-cement ratio are 0.04, 0.06, 0.075 and 0.085 per
cent for water-cement ratios of 0.4, 0.5, 0.6 and 0.7, respectively.
One of the reasons is that the density and composition of calcium
silicate formed at different water-cement ratios may be slightly
different. In general, a higher cement content increases the shrinkage
of concrete; the relative shrinkages of neat paste, mortar and concrete
may be of the order of about 5, 2 and 1. For given materials, however,
and a uniform water content, the shrinkage of concrete varies little for
a wide range of cement contents; a richer mix will have a lower
water-cement ratio and these factors offset each other.
Properties of Cement
Fineness
of cement seems to be a factor in shrinkage and particles coarser than
No. 200 sieve, which react with water very slowly, have a restraining
effect similar to that of aggregate. Thus, high-early-strength cement,
which is finely ground, shrinks about 10 per cent more than normal
cement. Low-heat and portland-pozzolan cements shrink a further 20 and
35 per cent, respectively. This is believed to be caused by larger
quantities of calcium silicate, the shrinking component, present in
them.
Type and Gradation of Aggregate
As
stated previously, the drying shrinkage of concrete is a fraction of
that of neat cement because the aggregate particles not only dilute the
paste but reinforce it against contraction. It has been shown that when
readily compressible aggregate is used concrete will shrink as much as
neat cement, and that expanded shale leads to shrinkage one-third more
than that of ordinary aggregate. Steel aggregate on the other hand,
leads to shrinkage one-third less than that of ordinary concrete. In
general terms the elastic properties of aggregate determine the degree
of restraint offered. The size and grading of aggregate do not, by
themselves, influence the magnitude of shrinkage, but an aggregate
incorporating larger sizes permits the use of a mix with less cement and
hence a lower shrinkage. Increasing the maximum aggregate size and
thereby the aggregate content by 20 per cent of the total volume of the
concrete will ensure a substantial decrease in shrinkage.
The
shrinkage of aggregates themselves may be of considerable importance in
determining the shrinkage of concrete; some fine-grained sandstones,
slate, basalt, trap rock and aggregates containing clay show large
shrinkage. In general, concretes low in shrinkage often contain quartz,
limestone, granite or feldspar. Various harmful effects of abnormal
shrinkage of concretes, caused by the aggregate and observed in actual
structures, have included excessive cracking, large deflection of
reinforced beams and slabs and some spalling. It is essential that any
new source of aggregate be tested to ascertain whether its use in
concrete will cause excessive shrinkage to develop. Any shrinkage in
excess of 0.08 per cent is taken to indicate an undesirable aggregate.
Effect of Admixtures
As
can be predicted from the effect of water-cement ratio on shrinkage,
admixtures that increase the water requirement of concrete increase
shrinkage and those that decrease the water requirement decrease it.
Calcium chloride in the amount often added as an accelerator – 2 per
cent by weight of the amount of cement – may increase drying shrinkage
by as much as 50 per cent.
The
over-all effect of the use of air entrained concrete is not to increase
shrinkage. Some admixtures, if used in somewhat larger than normal
doses, do increase shrinkage greatly and care must be exercised in the
proportioning.
Rate of Drying
The
size of the specimen and conditions of exposure are important in
assessing the relevance of the shrinkage problem. Drying of ordinary
concrete exposed to an environment maintained at 50 per cent RH will
affect moisture content to a depth of 3 in. in one month. Continued
exposure to these conditions would be a significant factor in small
concrete members but would be of no importance in massive elements.
Carbonation Shrinkage
Another
mechanism that will result in shrinkage of concrete is the reaction
between carbon dioxide and hydrated cement. Maximum shrinkage occurs
when the concrete is at equilibrium in a 50 per cent RH environment.
This shrinkage combined with drying shrinkage results in excessive
crazing of exposed surfaces such as concrete floors when CO2 levels are
high, a condition often found on winter construction projects.
Carbonation
during the curing of concrete products is sometimes used to encourage
shrinkage and thus reduce shrinkage stresses when these units are
incorporated into a structure. Carbonation also reduces permeability,
presumably due to deposition of the reaction products in the pores and
capillaries.
Creep of Concrete
Creep
of concrete resulting from the action of a sustained stress is a
gradual increase in strain with time; it can be of the same order of
magnitude as drying shrinkage. As defined, creep does not include any
immediate elastic strains caused by loading or any shrinkage or swelling
caused by moisture changes. When a concrete structural element is dried
under load the creep that occurs is one to two times as large as it
would be under constant moisture conditions. Adding normal drying
shrinkage to this and considering the fact that creep can be several
times as large as the elastic strain on loading, it may be seen that
these factors can cause considerable deflection and that they are of
great importance in structural mechanics.
If
a sustained load is removed, the strain decreases immediately by an
amount equal to the elastic strain at the given age; this is generally
lower than the elastic strain on loading since the elastic modulus has
increased in the intervening period. This instantaneous recovery is
followed by a gradual decrease in strain, called creep recovery. This
recovery is not complete because creep is not simply a reversible
phenomenon.
It
is now believed that the major portion of creep is due to removal of
water from between the sheets of a calcium silicate crystallite and to a
possible rearrangement of bonds between the surfaces of the individual
crystallites.
Factors Influencing Creep
Concrete
that exhibits high shrinkage generally also shows a high creep, but how
the two phenomena are connected is still not understood. Evidence
suggests that they are closely related. When hydrated cement is
completely dried, little or no creep occurs; for a given concrete the
lower the relative humidity, the higher the creep.
Strength
of concrete has a considerable influence on creep and within a wide
range creep is inversely proportional to the strength of concrete at the
time of application of load. From this it follows that creep is closely
related to the water-cement ratio. There is no doubt also that the
modulus of elasticity of aggregate controls the amount of creep that can
be realized and concretes made with different aggregates exhibit creep
of varying magnitudes.
Experiments
have shown that creep continues for a very long time; detectable
changes have been found after as long as 30 years. The rate decreases
continuously, however, and it is generally assumed that creep tends to a
limiting value. It has been estimated that 75 per cent of 20-year creep
occurs during the first year.
Effects of Creep
Creep
of plain concrete does not by itself affect strength, although under
very high stresses creep hastens the approach of the limiting strain at
which failure takes place. The influence of creep on the ultimate
strength of a simply supported, reinforced concrete beam subjected to a
sustained load is insignificant, but deflection increases considerably
and may in many cases be a critical consideration in design. Another
instance of the adverse effects of creep is its influence on the
stability of the structure through increase in deformation and
consequent transfer of load to other components. Thus, even when creep
does not affect the ultimate strength of the component in which it takes
place, its effect may be extremely serious as far as the performance of
the structure as a whole is concerned.
The
loss of prestress due to creep is well known and accounted for the
failure of all early attempts at prestressing. Only with the
introduction of high tensile steel did prestressing become a successful
operation. The effects of creep may thus be harmful. On the whole,
however, creep unlike shrinkage is beneficial in relieving stress
concentrations and has contributed to the success of concrete as a
structural material.